I downloaded some skyboxes from the Unity Store to make a night scene.
By setting a night skybox, it makes it all dark and this worked great; nothing can be seen without a light source!
But I made a really simple script to just change the default skybox to the night one, which accomplishes this, but you can still see everything in a grayish color.
Code
using UnityEngine;
using System.Collections;
public class SceneEditor : MonoBehaviour {
public Material skybox;
void Start () {
RenderSettings.skybox = skybox;
RenderSettings.ambientSkyColor = skybox.color;
}
}